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Research articles

ScienceAsia 52 (2026): 1-9 |doi: 10.2306/scienceasia1513-1874.2026.072


Interfacial modification of epoxy-coated coal gangue proppants using silane coupling agent


Xiaoyang Liua, Dongyan Fana, Zhongquan Fengb, Wei Liua, Jianbin Songa,*, Yu Lib,*

 
ABSTRACT:     Toenhance the mechanical properties of coal gangue ceramsite (CGC) proppants, a technology combining epoxy resin (EP) coating with silane coupling agent KH-792 was employed. Fourier transform infrared (FTIR) analysis confirms that while the epoxy resin forms a physical coating on the ceramsite surface, KH-792 participates in interfacial chemical reactions to construct a dense and rigid siloxane cross-linked network. Studies have shown that coal gangue proppants treated with silane coupling agent were greatly improved in terms of density, crushing rate, turbidity, and water absorption. The CGC proppants modified with a silane coupling agent display the best overall performance. Compared with the untreated CGC proppants, its bulk density falls from 1.56 g/cm3 to 1.43 g/cm3 and its apparent density from 2.61 g/cm3 to 2.43 g/cm3. Turbidity drops from 65.8 to 10.8 NTU, and 24-h water absorption decreases from 8.8% to 4.8%. Most importantly, the crushing ratio under 69 MPa declines from 3.04% to 2.46%. These improvements have broadened the application prospects of the coal gangue ceramsite proppants in the petroleum industry

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a Xinjiang Key Laboratory for Value-added Utilization of Heavy Carbon Resources, School of Chemistry and Chemical Engineering, Yili Normal University, Yining 835000 China
b State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083 China

* Corresponding author, E-mail: jianbin1102@163.com, leeuu00@sina.com

Received 16 Oct 2025, Accepted 29 Jun 2026