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Short Report

ScienceAsia 11 (1985): 183-188 |doi: 10.2306/scienceasia1513-1874.1985.11.183

 

INTRAMOLECULAR ACYLATION OF -(PHENYLSULFINYL) CARBANIONS: A CONVENIENT SYNTHESIS OF SUBSTITUTED CYCLOHEX-2-ENONES

 

MANAT POHMAKOTR, PRANEE PHINYOCHEEP and SIRIRAT CHANCHARUNEE

ABSTRACT: A convenient synthesis of substituted cyclohex-2-enones. which involves the intramolecular acylation of an -(phenylsulfinyl) carbanion followed by pyrolysis. is described.

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Department of Chemistry, Faculty of Science, Mahidol University, Rama VI Road, Bangkok 10400, Thailand.

Received 21 December 1984