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Research articles

ScienceAsia 51 (2026): 1-8 |doi: 10.2306/scienceasia1513-1874.2026.005


Electrochemical synthesis of nanodispersed zinc oxide using alternating current


Aizhan Mamyrbekovaa, Aigul Mamyrbekovaa,*, M.K. Kassymovab, A.D. Mamitovac, G.S. Mutashevad

 
ABSTRACT:      The possibility of obtaining nanodispersed zinc oxide by electrolysis on alternating current of industrial frequency was shown. The parameters of electrolysis, influencing the electrochemical oxidation of zinc in neutral solutions and the rate of formation of the zinc oxide powder were studied. The effect of electrolyte composition on the electrode process at a zinc electrode was investigated using polarization measurements. The electrochemical behavior of the zinc electrode in neutral sodium salt solutions in the concentration range of 0.4?4.0 mol/l, at temperature range of 20?50?C, and at 5 to 100 mV/s sweep rates was studied. The anodic potentiodynamic curves in 0.4 mol/l NaClO4 , CH3 COONH4 , Na2 SO4 , NaNO3 , and NaCl solutions were recorded. From the polarization curves, it was established that the rate of anodic ionization of zinc increases in the following series: CH3 COONH4 < NaClO4 < NaNO3 < Na2 SO4

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a Department of Fundamental Sciences, Faculty of Medicine, Khoja Akhmet Yassawi International Kazakh-Turkish University, Turkistan 161200 Kazakhstan
b Department of Food Engineering, Textile and Food Engineering Higher School, M. Auezov South Kazakhstan University, Shymkent 160012 Kazakhstan
c Department of Life Safety and Environmental Protection, Faculty of Architecture, Construction and Transport, M. Auezov South Kazakhstan University, Shymkent 160012 Kazakhstan
d Department of Soil Science, Agrochemistry and Ecology, Faculty of Agrobiology, Kazakh National Agrarian Research University, Almaty 050010 Kazakhstan

* Corresponding author, E-mail: aigul.mamyrbekova@ayu.edu.kz

Received 8 Jan 2024, Accepted 0 0000